Recycled Newspaper Fiber/Polypropylene Composites with Inorganic Flame Retardants: Flame Retardant and Mechanical Characteristics

Authors

  • Haydar U. Zaman Department of Physics, National University of Bangladesh, Gazipur, Dhaka, Bangladesh AND Institute of Radiation and Polymer Technology, Bangladesh Atomic Energy Commission, P.O. Box-3787, Savar, Dhaka, Bangladesh https://orcid.org/0000-0002-1673-6915
  • Ruhul A. Khan Institute of Radiation and Polymer Technology, Bangladesh Atomic Energy Commission, P.O. Box-3787, Savar, Dhaka, Bangladesh

DOI:

https://doi.org/10.22034/advjse042014

Keywords:

Flame retardancy, Flammability, Mechanical properties, Polypropylene, Recycled newspaper fiber/PP composite

Abstract

This study intends to look at ways to increase the flame retardancy of composite materials made of recycled newspaper fiber (RNF) and polypropylene (PP) matrix. A melt-blending approach followed by injection molding was used to create PP/RNF composites, which have various advantages including low cost, the ability to dispose of industrial waste, and good mechanical properties. Different types and concentration of flame retardants, such as magnesium hydroxide (Mg(OH)2) with smaller particle size and zinc borate with antimony trioxide (ZB-AT), were utilized to increase the flame resistance of the composites. The UL94 test was used to assess the composites' flame resistance. In comparison to pure PP, composite blends of PP/RNF/Mg(OH)2 and PP/RNF/ZB-AT are more fire resistant. Depending on the application, the resulting composite may have different amounts of both elements. Although effects on tensile and impact strength have not been discussed, research has been done and publications have been made regarding improvements in the fire retardant properties of such composites. The strength of the PP/RNF/Mg(OH)2 and PP/RNF/ZB-AT composites were discussed in relation to the effects of Mg(OH)2 and ZB-AT concentration. Study and discussion were conducted about the tensile, flexural, and impact properties. With the addition of flame-retardants, a little drop in the mechanical characteristics of the composites was observed.

 

References

Tan TTM. Thermoplastic composites based on jute fibre treated with cardanol-formaldehyde. Polymers and Polymer Composites. 1997; 5: 273.

Yadav P, Nema A, Varghese S, Nema SK. Newspaper?reinforced plastic composite laminates: mechanical and water uptake characteristics. Polymer Engineering & Science. 1999; 39: 1550.

Ismail H, Salmah, Bakar AA. The effect of paper sludge content and size on the properties of polypropylene (PP)-ethylene propylene diene terpolymer (EPDM) composites. Journal of Reinforced Plastics and Composites. 2005; 24: 147.

Yuan X, Zhang Y, Zhang X. Maleated polypropylene as a coupling agent for polypropylene–waste newspaper flour composites. Journal of Applied Polymer Science. 1999; 71: 333.

Zaman HU, Khan RA. Effect of fiber surface modifications on the properties of snake grass fiber reinforced polypropylene bio-composites. Journal of Adhesion Science and Technology. 2022; 36: 1439.

Zaman HU, Khan RA. Surface modification of plant-drive calotropis gigantea fiber reinforced polypropylene composites. Progress in Applied Science and Technology. 2020; 12: 23.

Zaman HU, Khan RA. Surface modified benzoylated okra (abelmoschus esculentus) bast fiber reinforced polypropylene composites. Advanced Journal of Science and Engineering. 2022; 3: 7.

Zaman HU, Khan RA, Chowdhury AM. The improvement of physicomechanical, flame retardant, and thermal properties of lignocellulosic material filled polymer composites. Journal of Thermoplastic Composite Materials. 2023; 36: 1034.

Zaman H, Khan RA. Fabrication and study of natural plant fiber reinforced polymer composites. International Journal of Polymer Science & Engineering. 2021; 7: 11.

Arbelaiz A, Fernandez B, Ramos JA, Retegi A, Llano-Ponte R, Mondragon I. Mechanical properties of short flax fibre bundle/polypropylene composites: Influence of matrix/fibre modification, fibre content, water uptake and recycling. Composites Science and Technology. 2005; 65: 1582.

Arbelaiz A, Fernández B, Cantero G, Llano-Ponte R, Valea A, Mondragon I. Mechanical properties of flax fibre/polypropylene composites. Influence of fibre/matrix modification and glass fibre hybridization. Composites Part A: Applied Science and Manufacturing. 2005; 36: 1637.

Demir H, Atikler U, Balkose D, T?hm?nl?oglu F. The effect of fiber surface treatments on the tensile and water sorption properties of polypropylene–luffa fiber composites. Composites Part A: Applied Science and Manufacturing. 2006; 37: 447.

Son J, Yang HS, Kim HJ. Physico-mechanical properties of paper sludge-thermoplastic polymer composites. Journal of Thermoplastic Composite Materials. 2004; 17: 509.

Zaman HU, Khan RA. Effect of compatibilizing agents on organoclay dispersion of polypropylene/organoclay nanocomposites. Progress in Applied Science and Technology. 2021; 11: 9.

Zaman HU, Khan RA. Compatibilizing effect of modified polypropylene on the properties of polypropylene/organically modified layered silicate nanocomposites. International Journal of Composite Materials and Matrices. 2021; 7: 8.

Zaman HU. Influences of layered silicate modification and compatibilizers on the properties of polypropylene nanocomposites. International Journal of Chemical Engineering and Processing. 2021; 7: 36.

Simitzis J, Karagiannis K, Zoumpoulakis L. Influence of biomass on the curing of novolac-composites. European Polymer Journal. 1996; 32: 857.

Kim JK, Pal K. Recent advances in the processing of wood-plastic composites. NY: Springer. 2010.

Turi EA. Thermal characterization of polymeric materials. NY: Academic Press. 1981.

Hilado CJ. Flammability handbook for plastics. PA: CRC Press. 1998.

Rigolo M, Woodhams R. Basic magnesium carbonate flame retardants for polypropylene. Polymer Engineering & Science. 1992; 32: 327.

Montezin F, Cuesta JM, Crespy A, Georlette P. Flame retardant and mechanical properties of a copolymer PP/PE containing brominated compounds/antimony trioxide blends and magnesium hydroxide or talc. Fire and Materials. 1997; 21: 245.

Cross MS, Cusack PA, Hornsby PR. Effects of tin additives on the flammability and smoke emission characteristics of halogen-free ethylene-vinyl acetate copolymer. Polymer Degradation and Stability. 2003; 79: 309.

Jang J, Lee E. Improvement of the flame retardancy of paper-sludge/polypropylene composite. Polymer Testing. 2000; 20: 7.

Macskay H, Palyi G. Plastics their behaviour in fires. Amsterdam: Elsevier. 1991.

US Industry Forecasts to 2011 and 2016 “Glass Fibers” Freedonia. 2007.

Al-Mosawi A. Study using of antimony trioxide material as a flame retardant material. Master of Science Thesis. Engineering College: Babylon University. Iraq. 2003.

Myszak Jr E. Use of submicron inorganic flame retardants in polymeric systems. 1992.

Jang J, Chung H, Kim M, Sung H. The effect of flame retardants on the flammability and mechanical properties of paper-sludge/phenolic composite. Polymer Testing. 2000; 19: 269.

Kozlowski R, Mieleniak B, Helwig M, Przepiera A. Flame resistant lignocellulosic-mineral composite particleboards. Polymer Degradation and Stability. 1999; 64: 523.

Titelman GI, Gonen Y, Keidar Y, Bron S. Discolouration of polypropylene-based compounds containing magnesium hydroxide. Polymer Degradation and Stability. 2002; 77: 345.

Innes J, Innes A. Compounding metal hydrate flame retardants. Plastics, Additives and Compounding. 2002; 4: 22.

Rothon R, Hornsby P. Flame retardant effects of magnesium hydroxide. Polymer Degradation and Stability. 1996; 54: 383.

Wilkie CA, Morgan AB. Fire retardancy of polymeric materials. NY: CRC press. 2009.

Chiu SH, Wang WK. The dynamic flammability and toxicity of magnesium hydroxide filled intumescent fire retardant polypropylene. Journal of Applied Polymer Science. 1998; 67: 989.

Downloads

Published

2023-05-01

How to Cite

Zaman, H., & Ruhul. (2023). Recycled Newspaper Fiber/Polypropylene Composites with Inorganic Flame Retardants: Flame Retardant and Mechanical Characteristics. Advanced Journal of Science and Engineering, 4(2), 042014. https://doi.org/10.22034/advjse042014

Issue

Section

Original Research Article