Probing the Binding Fashion in Coordination Compounds of D-Block Metals with Versatile Dithiocarbamate N and S Containing Ligand
DOI:
https://doi.org/10.22034/AJSE2011012Keywords:
Transition metal, Dithiocarbamate, Metal complexAbstract
The synthesis of sulfur and nitrogen (S and N) containing dithiocarbamate ligand derived from 1-naphthylylamine as well as its coordination compounds with d-block metals of first series have been described. These synthesized compounds were characterized through elemental analysis, conductometric measurements and IR spectral studies. The analytical data showed that the stoichiometry should be 1:2 and 1:3 for the compounds of the types ML2 {M=Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)} and M’L3 {M’=Cr(III) and Fe(III)}, respectively. The conductometric measurements indicated that the compounds are non-ionic in nature. The bidentate nature of dithiocarbamate moiety was confirmed on the basis of FT-IR spectral analysis.
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